OPPORTUNITIES FOR BY-PROCESS EXTRACTION OF MOLYBDENUM FROM BLACK SHALE ORES
Kurbanov Mashhur Amonovich
Doctor of Philosophy, Deputy Head of the Mining Laboratory NMMC JSC
Keywords: Black shales, molybdenum, ammonia-carbonate solution, organic phase, extract, strip, trioxide, precipitation, ammonium paramolybdate.
Abstract
The article presents the results of a study of the possibility of extracting molybdenum from the products of processing refractory black shale ores. The analysis showed high molybdenum concentrations in the recycled ammonia-carbonate solutions at the stripping stage. A liquid extraction method was studied to extract molybdenum from these solutions. A process flow chart for molybdenum extraction is described, including the following main stages: deoxidation of carbonate solutions with sulfuric acid to pH = 1, joint extraction of uranium and molybdenum, selective stripping of molybdenum, neutralization of strips and production of ammonium paramolybdate.
References
Tagayev I.A, Sharipov S.S, Doniyorov N.A Noyob va radioaktiv metallarning kimyoviy texnologiyasi // Navoiy-2021 y. – 257-280 b.
Greenwood, N. N., & Earnshaw, A. (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. S-52-90.
Cotton, F. A., Wilkinson, G., Murillo, C. A., & Bochmann, M. (1999). Advanced Inorganic Chemistry (6th ed.). Wiley-Interscience. S-122-192.
Kolditz, L. (1993). Anorganische Chemie. VEB Deutscher Verlag für Grundstoffindustrie.
Kibby, C. L. (2019). The Chemistry and Applications of Molybdenum and Its Compounds. Springer.
Gmelin, L. (1994). Handbook of Inorganic Chemistry: Molybdenum. Springer-Verlag.С-1-200.
Ya.E.Yudovich, M.P.Ketris Geochemistry of black shales. L. Nauka, 1988.
Kurbanov M.A., Ruziev B.T., Ikramov D.Z., Nurmukhamadova N.E. On the issue of vanadium extraction from refractory black shale ores. Mining Bulletin of Uzbekistan. - 2023. - No. 1. - P.57-59.
Oslopovsky S.A., Kurbanov M.A., Ochilova I.D., Nurmukhamadova N.E., Yusupova S.S., Ibragimov R.R., Yuldashev Sh.Sh. Development of technology for producing vanadium pentoxide from technogenic raw materials // UNIVERSUM: Technical sciences - Moscow, 2023. - No. 2 (107) P. 78-86.